►Google Scholar Profile ►ORICD (NOTE: * Corresponding Author; # Equal Contribution)
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38. Jingwen Li (李静雯), Ziqi Zhang, Zenghui Li, Jing Wang, Changyuan Xu, Jie Xiong, Ling Yue and Bin Rao*, D–A Radicals Fabricated from Polychlorinated Trityl and Pyridinium Featuring a Somo–Lumo Electronic Transition. Chem. Commun. 2026, 62, 7558. https://pubs.rsc.org/en/content/articlelanding/2026/cc/d6cc00928j
37. Kaixing Gu (谷开兴), Zenghui Li, Jing Wang, Changyuan Xu, Pin Gao, and Bin Rao*， Engineering Air-Stable, Near-Infrared Luminescent Trityl Radicals with One Phenothiazine Ring, Chin. J. Chem. 2026, 11. 1351. (Invited paper) https://onlinelibrary.wiley.com/doi/full/10.1002/cjoc.70470
36. Jing Wang (王静), Zenghui Li, Kaixing Gu, Changyuan Xu, Jie Xiong, Tian Han, Ling Yue, and Bin Rao*，Air-Stable and Luminescent Trityls via Methoxy Modification, Org. Lett. 2026, 28, 1, 360–365. https://pubs.acs.org/doi/10.1021/acs.orglett.5c04774
35. Pengfei Dong (董鹏飞), Zenghui Li, Kaixing Gu, Liang Xu,* Yu Wei,* Jing Wang, Ling Yue, and Bin Rao*, Engineering Air-Stable Triarylmethyl Radicals with One Pyrrole Ring, Org. Lett. 2025, 27, 686–691. https://pubs.acs.org/doi/10.1021/acs.orglett.4c04590
34. Shuangjing Zhou; Xin Liu; Bin Rao; Shujiang Ding; Garret M. Miyake; Rong Zeng, Iron-Catalyzed C–H Amination of Polyethylenes, Macromolecules 2025, 58, 8877–8886. https://pubs.acs.org/doi/10.1021/acs.macromol.5c00915
33. Shuangjing Zhou, Shaohong Wang, Cong Yu, Pengchen Ma,* Bin Rao, and Rong Zeng*， C─H Amination of Polypropylene with Sodium N-Chloro-Amides. Angew. Chem. Int. Ed.2025, 64, e202516324. https://onlinelibrary.wiley.com/doi/10.1002/anie.202516324
32. Zenghui Li (李增辉),# Xiaoyang Liu (刘晓杨),# Qidi Bao, Jing Wang, Xu Liu, Honghong Gong, Tian Han, Chao Feng, Dongmei Lu, Ling Yue, Chao Wu, Gang He,* Yuanting Su,* and Bin Rao*, The SUMO (Singly Unoccupied Molecular Orbital)-LUMO (Lowest Unoccupied Molecular Orbital) Inversion Radicals, J. Am. Chem. Soc.2025, 147, 1452–1457. X-MOL资讯：SUMO-LUMO能级反转的有机自由基
~~~2024year~~~
31. Jing Wang (王静),# Zenghui Li (李增辉),# Xiaoyang Liu, Bochao Su, Honghong Gong, Chao Feng, Guoping Li, Gang He* and Bin Rao*, Fine-tuning redox ability of arylene-bridged bis(benzimidazolium) for electrochromism and visible-light photocatalysis, Chin. Chem. Lett.2024, 35, 109473.
30. Jiawei Fan, Ling Yue, Ce Liu, Bin Rao, Guijiang Zhou, Anyang Li*, and Bochao Su,* Isolation of Fluorescent 2π-Aromatic 1,3-Disiladiboretenes, J. Am. Chem. Soc.2024, 146, 1, 39–44.
29. Yulong Wang, Shenyu Shen, Chonglong He, Youkang Zhou, Keyuan Zhang, Bin Rao, Tian Han, Yaqiong Su, Xin-Hua Duan, Le Liu,* Cu(ii)-mediated direct intramolecular cyclopropanation of distal olefinic acetate: access to cyclopropane-fused γ-lactones,Chem. Sci., 2023,14, 6663-6668
28.Zenghui Li (李增辉), Jing Wang, Xiaoyang Liu, Pin Gao, Guoping Li, Gang He* and Bin Rao*, Air-stable Organoradical Boron Reagents, Angew. Chem. Int. Ed.2023, e202302835. https://onlinelibrary.wiley.com/doi/abstract/10.1002/anie.202302835 CBG资讯：空气稳定的有机自由基硼试剂合成与转化
27.Jing Wang (王静), Zenghui Li, Gaoqiang You, Liang Xu, Pin Gao and Bin Rao*, Regioselective transformation of 3-phosphoryl benzyne intermediates to diverse phosphorus-substituted arenes. New J. Chem. 2022, 46, 17049-17054. https://pubs.rsc.org/en/content/articlelanding/2022/NJ/D2NJ03638J
26.Wenqiang Ma, Sikun Zhang, Liang Xu, Bingjie Zhang, Guoping Li, Bin Rao*, Mingming Zhang, Gang He*. Pyrene-tethered bismoviologens for visible light-induced C(sp3)–P and C(sp2)–P bonds formation, Chin. Chem. Lett.2022, 107958.
25.Guoping Li, Kun Zhou, Qi Sun, Wenqiang Ma, Xu Liu, Xuri Zhang, Lei Zhang, Bin Rao, Ya-Ling He and Gang He*. Bacteria-Triggered Solar Hydrogen Production via Platinum(II) Tethered Chalcogenoviologens. Angew. Chem. Int. Ed.2022, 61, e2021152.
24. Ben He, Sikun Zhang, Yueyan Zhang, Guoping Li, Bingjie Zhang, Wenqiang Ma, Bin Rao, Ruitong Song, Lei Zhang, Yanfeng Zhang and Gang He*. ortho-Terphenylene Viologens with Through-Space Conjugation for Enhanced Photocatalytic Oxidative Coupling and Hydrogen Evolution. J. Am. Chem. Soc. 2022, 144, 4422-4430.
23. Xiaodong Yang, Bingjie Zhang, Yujing Gao, Chenjing Liu, Guoping Li,* Bin Rao, Dake Chu, Ni Yan, Mingming Zhang, and Gang He*. Efficient Photoinduced Electron Transfer from Pyrene-o-Carborane Heterojunction to Selenoviologen for Enhanced Photocatalytic Hydrogen Evolution and Reduction of Alkynes，Adv. Sci.2021, 2101652
22. Letian Xu, Kun Zhou, Xinyu Qiu, Bin Rao, Dandan Pei, Ang Li, Zhongfu An, Gang He, Tunable ultralong organic phosphorescence modulated by main-group elements with different Lewis acidity and basicity, J. Mater .Chem. C 2020, 8, 14740-14747.
21. Ruitong Song, Guoping Li, Yueyan Zhang, Bin Rao, Shanxin Xiong, Gang He*, Novel Electrochromic Materials Based on Chalcogenoviologens for Smart Windows, E-Price Tag and Flexible Display with Improved Reversibility and Stability, Chemical Engineering Journal, 2021, 130057
20. Sikun Zhang, Xiaodong Yang, Xu Liu, Letian Xu, Bin Rao, Ni Yan and Gang He*. Dithienoazaborine derivatives with selective π-conjugated extension via late-stage functionalization J. Mater. Chem. C, 2021, 9, 4053-4061
19. Qiang Zhang, Shujuan Wang, Bin Rao, Xingxing Chen, Li Ma, Chenhui Cui, Qianyun Zhong, Zhen Li, Yilong Cheng and Yanfeng Zhang*, Hindered urea bonds for dynamic polymers: An overview, Reactive and Functional Polymers2021, 159, 104807.
18. Wenqiang Ma, Letian Xu, Sikun Zhang, Guoping Li, Tianyu Ma, Bin Rao, Mingming Zhang, and Gang He*, Phosphorescent Bismoviologens for Electrophosphorochromism and Visible Light-Induced Cross-Dehydrogenative Coupling, J. Am. Chem. Soc.2021, 143, 1590–1597.
Befor XJTU
17.Bin Rao and Rei Kinjo*, Crystalline Boragermenes, Angew. Chem. Int. Ed.2020, 59, 3147–3150.
16.Bin Rao and Rei Kinjo*, A Cyclic (Alkyl)(boryl)germylene Derived from a Cyclic (Alkyl)(amino)germylene, Angew. Chem. Int. Ed. 2019, 58, 18150–18153.
15. Bin Rao, Liliang Wang, Rei Kinjo*, Borane-Catalyzed Cross-Metathesis Strategy for Facile Transformation of Cyclic (Alkyl)(Amino)Germylenes, Angew. Chem. Int. Ed.2019, 58, 231–235.
14. Bin Rao, Che Chang Chong, Rei Kinjo*, Metal-Free Regio- and Chemoselective Hydroboration of Pyridines Catalyzed by 1,3,2-Diazaphosphenium Triflate, J. Am. Chem. Soc. 2018, 140, 652–656.
13.Bin Rao, Rei Kinjo*, Boron-Based Catalysts for C−C Bond Formation Reactions, Chem. Asian J.2018, 1279–1292.
12. Che Chang Chong(#), Bin Rao(#), Rei Kinjo*, Metal-Free Catalytic Reduction of a,b-Unsaturated Esters by 1,3,2-Diazadiphospholene and Subsequent C–C Coupling with Nitriles, ACS Catal. 2017, 7, 5814–5819.
11. Che Chang Chong, Bin Rao, Yongxin Li, Rakesh Ganguly, Rei Kinjo*, Bis(N-heterocyclic olefin) Derivative: An Efficient Precursor for Isophosphindolylium Species, Inorg. Chem. 2017, 56, 8608–8614.
10. Bin Rao, Jinhua Tang, Xiaoming Zeng*, Synthesis of 2-Benzylphenyl Ketones by Aryne Insertion into Unactivated C–C Bonds, Org. Lett. 2016, 18，1678–1681.
9. Bin Rao, Jinhua Tang, Yu Wei, Xiaoming Zeng*, Ring Expansion via Cleavage of Benzylic C-C Bonds Enabling Direct Synthesis of Medium Ring-fused Benzocarbocycles, Chem. Asian J. 2016, 991–995.
8. Bin Rao, Huarong Tang, Xiaoming Zeng*, Liu Liu, Mohand Melaimi, Guy Bertrand*, Cyclic (Amino)(aryl)carbenes (CAArCs) as Strong s-Donating and p-Accepting Ligands for Transition Metals, Angew. Chem. Int. Ed. 2015, 54, 14915–14919.
7. Yu Wei, Bin Rao, Xuefeng Cong, and Xiaoming Zeng*, Highly Selective Hydrogenation of Aromatic Ketones and Phenols Enabled by Cyclic (Amino)(alkyl)carbene Rhodium Complexes, J. Am. Chem. Soc. 2015, 137, 9250–9253.
6. Weixi Zhang, Junyao Xie, Bin Rao, and Meiming Luo*, Iron-Catalyzed N-Arylsulfonamide Formation through Directly Using Nitroarenes as Nitrogen Sources, J. Org. Chem.,2015, 80, 3504–3511.
5. Bin Rao and Xiaoming Zeng*, Aminocyanation by the Addition of N–CN Bonds to Arynes: Chemoselective Synthesis of 1,2-Bifunctional Aminobenzonitriles, Org. Lett. 2014, 16, 314–317.
4. Yu Wei, Huarong Tang, Xuefeng Cong, Bin Rao, Chao Wu* and Xiaoming Zeng*,Pd(II)-Catalyzed Intermolecular Arylation of Unactivated C(sp3)–H Bonds with Aryl Bromides Enabled by 8-Aminoquinoline Auxiliary, Org. Lett. 2014, 16, 2248–2251.
3. Bin Rao, Weixi Zhang, Lan Hu and Meiming Luo*，Catalytic desulfitative homocoupling of sodium arylsulfi nates in water using PdCl2 as the recyclable catalyst and O2 as the terminal oxidant, Green Chem. 2012, 14, 3436–3440.
2. Guangming Nan, Bin Rao，Meiming Luo*, Cis-chelated palladium(II) complexes of biphenyl-linked bis(imidazolin-2-ylidene): synthesis and catalytic activity in the Suzuki-Miyaura reaction, ARKIVOC, 2011, ii, 29–40. 1.
1. Xiaoqin Zhang, Yuping Qiu, Bin Rao, and Meiming Luo*, Palladium(II)−N-Heterocyclic Carbene Metallacrown Ether Complexes: Synthesis, Structure, and Catalytic Activity in the Suzuki−Miyaura Reaction, Organometallics 2009, 28, 3093–3099.