Reaction mechanism of borane/oxygen radical initiators during the polymerization of fluoromonomers
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发布时间：2025-04-30
发布时间：2025-04-30
论文名称：Reaction mechanism of borane/oxygen radical initiators during the polymerization of fluoromonomers
发表刊物：Macromolecules
摘要：In summary, the combined information from oxidation adducts of two related boranes (triethylborane and diethyl-methoxylborane) and the polymer chain end structure presents a complete picture of oxidation and the initiation mechanism of broane/oxygen-mediated radical polymerization of fluo-romonomers at ambient temperature. This borane/oxygen initia-tor offers a safe and effective route to prepare fluoropolymers with high molecular weights and high purities. It also provides the control of polymer chain end structure by initiator.
合写作者：Zhicheng Zhang; T.C. Mike Chung
卷号：Volume: 39 Issue: 16
页面范围：5187-5189
是否译文：否
发表时间：2006-06-29