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Tao Zhang published a new article on CrystEngComm

发布时间:2019-06-14
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发布时间:
2019-06-14
文章标题:
Tao Zhang published a new article on CrystEngComm
内容:
Tao Zhang published a new article on CrystEngComm. Congratulation!
Title: An anionic manganese(II) metal–organic framework for uranyl adsorption
 
Abstract
We report herein that an anionic metal–organic framework [Mn5(izdc)3(ox)3] can adsorb uranyl in water with high selectivity (Kd = 2041 mL·g−1), large capacity (523 mg· g−1) and fast dynamics (KS = 6.68 × 10−3 mg·g−1·min−1). Grand canonical Monte Carlo simulation reveals that the coordination effect between the carboxylate O atoms and the equatorial position of the uranyl ion is the key behind this high-performance.