表面介导配体解决室温合成无机钙钛矿纳米晶向高效发光二极管发展的瓶颈 (代锦飞 Nano Energy 70 (2020) 104467）
- 发布时间：
- 2020-02-20
- 文章标题：
- 表面介导配体解决室温合成无机钙钛矿纳米晶向高效发光二极管发展的瓶颈 (代锦飞 Nano Energy 70 (2020) 104467）
- 内容：
Cesium lead halide perovskites (CsPbX3) have become superior candidates for perspective optoelectronic applications. However, room temperature synthesized CsPbX3 nanocrystals (NCs) suffer from serious lattice/surface traps, mostly induced by nonequilibrium reactions and polar solvent systems. Thus, direct assembly of such poor crystals cannot be available toward high efficiency light emitting diodes (LEDs). To address this issue, differing from the general post-treatment works, here we propose a double-terminal diamine bromide salt to in situ passivate the surface traps of room temperature synthesized CsPbBr3 NCs. High-quality NC solutions with photoluminescence quantum yield (PLQY) beyond 90% are obtained owing to the renovated surface bromide vacancies. Meanwhile, instead of longer oleylamine (OLA) ligand, the abridged diamine bromine ligand could
significantly enhance charge transport throughout the NC film. In addition, the NC based LED performance is found related to chain length of the ligand, where the optimal luminance of 14021 Cd m-2 and current efficiency of 25.5 Cd A-1 are achieved by 1, 4-butanediamine bromide passivated NC devices. This work provides a direct efficient approach to meet the device application of room temperature synthesized perovskite NCs, underlines the significance of selective ligands to address the challenges of NC emitters in future displays and solid-state lighting.