Kinetics investigation on the combustion of biochar in O2/CO2 atmosphere
发布时间：2025-04-30
点击次数：
- 发布时间：
- 2025-04-30
- 论文名称：
- Kinetics investigation on the combustion of biochar in O2/CO2 atmosphere
- 发表刊物：
- Environmental Progress & Sustainable Energy
- 摘要：
- Oxy-biomass combustion produces negative CO2 emissions. This study investigated the combustion kinetics of biochar in O2/CO2 atmosphere using a thermo-gravimetric analyzer. The effects of atmosphere, O2 concentration, and fuel type were considered in this investigation. Results show that the reaction order of biochar combustion ranges from 0.5 to 1. Furthermore, the kinetic compensation effect can be observed between the apparent activation energy E and the frequency factor A. This relation is given by lnA = 0.181E − 14.618. Compared with O2/N2 atmosphere, O2/CO2 atmosphere delays biochar ignition and reduces activation energy. The ignition temperature of straw char is significantly lower than that of wood and coal char. The apparent activation energy of char combustion follows the inequality wood char > straw char > coal char. This result indicates that biochar combustion is more sensitive to temperature than coal char combustion. The reactivity of char combustion improves with increasing O2 concentration, but biochar has a lower degree of improvement than coal char. The change from air combustion to oxy-fuel combustion and the increase in O2 concentration exert minimal effects on biochar combustion than on coal char combustion.
- 合写作者：
- Xuebin Wang, Zhongfa Hu, Shuanghui Deng, Yibin Wang, Houzhang Tan
- 卷号：
- 34（03）
- 页面范围：
- 923-932
- 是否译文：
- 否
- 发表时间：
- 2014-11-28