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Migration Behavior of Trace Elements at a Coal-fired Power Plant with Different Boiler Loads

  • Release Time:2025-04-30
  • Hits:
  • Date: 

    2025-04-30
  • Title of Paper: 

    Migration Behavior of Trace Elements at a Coal-fired Power Plant with Different Boiler Loads
  • Journal: 

    energy&fuels
  • Summary: 

    Trace  elements  (TEs)  emitted  from  the  coal-fired  power  has  done  great  harm  on  the environment,  which  causes  widespread  concern  in  the  world.  In  this  study,  the  effects  of  boiler loads (100% and 75% output) on the migration behaviors of TEs (including Cr, Mn, Co, Ni, Cu, Zn,  As,  Ba,  Pb)  were  conducted  on  a  coal-fired  power  plant  with  selective  catalytic  reduction (SCR), electrostatic precipitator (ESP), wet flue gas desulfurization (WFGD), and wet electrostatic precipitator  (WESP).  Simultaneous  sampling  of  coal,  bottom  and  fly  ash,  flue  gas,  and  the byproducts from WFGD and WESP was performed. It shows that mass balance rate of TEs at the two loads is in the acceptable range. TEs mainly distribute in bottom and ESP ash in the coal-fired power  plant  at  the  two  loads.  Compared  to  the  100%  load,  the  amount  of  TEs  in  bottom  ash increases at the 75% load. The overall removal rates of TEs through the whole system at the two
    loads are higher than 99.9%. Except Co and Ba, the overall removal rate at the 100% load is more than  that  at  the  75%  load.  The  ability  of  the  ESP  to  capture  particulate  TEs  at  the  75%  load  is lower than that at the 100% output while it is adverse for the gaseous TEs apart from As. WFGD and  WESP  have  the  synergistic  effects  to  remove  the  total  TEs.  TEs  may  re-emit  in  the desulfurization process. There  is  little  impact  on  the  enrichment  of TEs  in  ESP  and bottom  ash when  the  load  changes.  Concentration  of  TEs  emitted  to  the  atmosphere  is  in  the  range  of 0.01-1.76µg/m3 and 0.01-2.32µg/m3, respectively at the two loads in the gaseous form, which is extremely low. At last, the further work in the TEs’ removal is proposed.
  • Co-author: 

    Shilin Zhao, Yufeng Duan, Chenping Wang, Meng Liu, Jianhong Lu, Houzhang Tan, Xu
  • Volume: 

    Accepted
  • Translation or Not: 

    No
  • Date of Publication: 

    2016-12-25