High electrostrictive coefficient Q33 in lead-free Ba(Zr0.2Ti0.8)O3-x(Ba0.7Ca0.3)TiO3 piezoelectric ceramics.

Release Time:2025-04-30  Hits:

• Date:2025-04-30
• Title of Paper:High electrostrictive coefficient Q33 in lead-free Ba(Zr0.2Ti0.8)O3-x(Ba0.7Ca0.3)TiO3 piezoelectric ceramics.
• Journal:Applied Physics Letters
• Summary:In this study, the electrostrictive effect in Ba(Zr0.2Ti0.8)O3-x(Ba0.7Ca0.3)TiO3 (BZT-xBCT, x = 0.4, 0.5, and 0.6) ceramics was investigated to gain understanding of their high piezoelectric activity. The electrostrictive coefficient Q33 of the BZT-xBCT ceramics was observed to be around 0.04 m4/C², twice that reported for Pb(Zr,Ti)O3-based ceramics. The Q33 was found to be quite stable with respect to temperature and composition for the BZT-xBCT ceramics. The addition of Fe3+ dopant to the ceramics greatly decreased their Curie temperature without affecting their Q33, which remained 0.04 m4/C². Moreover, a high and hysteresis-free electric-field-induced strain was obtained for 2 at.% Fe-doped BZT-0.5BCT ceramics at room temperature, caused by their high Q33 coefficient and lower-than-room-temperature Curie temperature. The small-signal M33 coefficient of 2 at.% Fedoped BZT-0.5BCT ceramics was found to be 1.5 x 10--16 m²/V² (0.32 x 10--16 m²/V² for undoped counterpart). These results indicate that 2 at.% Fe-doped BZT-0.5BCT ceramics have great potential as alternatives for hard Pb(Zr,Ti)O3 ceramics in actuator applications, where reproducible and non-hysteretic deformation responses are required.
• Co-author:Li F, Jin L and Guo Runping.
• Volume:Vol. 105 Issue 23
• Page Number:1-4,
• Translation or Not:No
• Date of Publication:2014-12-05