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Bamboo-like amorphous carbon nanotubes clad in ultrathin nickel oxide nanosheets for lithium-ion battery electrodes with long cycle life

Release Time:2025-04-30
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Date:
2025-04-30
Title of Paper:
Bamboo-like amorphous carbon nanotubes clad in ultrathin nickel oxide nanosheets for lithium-ion battery electrodes with long cycle life
Journal:
CARBON
Summary:
In this work, we report the synthesis of one-dimensional (1-D) hierarchical NiO nanosheets covering bamboo-like amorphous CNT composites (NiO@CNT) via a facile and a low-cost solution route based on sulfonated polymeric nanotubes (PNTs) used simultaneously as both, a template, and a source of nano-structured carbon derived by a low-temperature thermal carbonization treatment. The electrochemical performance of the NiO@CNT composite electrode indicate that this novel hybrid nanostructure is potentially capable of delivering excellent reversible capacity when used as an anode material in a lithium-ion battery (LIB). A large discharge capacity of 1034 mAh g(-1) is delivered by the NiO@CNT composite even after 300 cycles at a relatively high current density of 800 mA g(-1), with an average coulombic efficiency of 98.1%. A significant achievement in the reversible capacity of the NiO@CNT composite is attributed to the outstanding nanostructure resulting in synergistic effects of the hollow amorphous CNT backbone and ultrathin NiO nanosheets. Furthermore, the generic solution method to fabricate 1-D metal oxides@amorphous CNT nanostructures, developed in this work, is expected to have a wide range of applications in improving the properties of transition metal oxides.
Co-author:
Xu, Xin; Tan, Hui; Xi, Kai; Ding, Shujiang; Yu, Demei; Cheng, Shaodong
Translation or Not:
No
Date of Publication:
2015-04-01